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The isotopic composition of barium (δ¹³⁸Ba) has emerged as a powerful tracer of deep-ocean circulation, water mass provenance, and the oceanic Ba cycle. Although the δ¹³⁸Ba of water masses is primarily controlled by the balance between pelagic barite precipitation and Ba resupply from ocean circulation, questions remain regarding the isotopic offset associated with pelagic barite formation and how the resultant Ba isotope compositions are transmitted through the water column to marine sediments. To address these questions, we conducted a time series study of dissolved, particulate, and sedimentary Ba chemistry in the Gulf of Aqaba (GOA), in the northern Red Sea, from January 2015 to April 2016. These data span significant seasonal changes in hydrography, primary productivity, and aerosol deposition, revealing three principal findings. First, the dissolved Ba chemistry of the GOA is vertically uniform across the time series, largely reflecting water mass advection from the Red Sea, with mean dissolved Ba concentrations of 47.9 ± 4.7 nmol kg⁻¹and mean δ¹³⁸Ba = +0.55‰ ± 0.07‰ (±2 SD,n= 18). Second, despite significant variations in particulate matter composition and flux, the δ¹³⁸Ba of sinking particulate Ba maintained a consistent isotope composition across different depths and over time at +0.09‰ ± 0.06‰ (n= 26). Consequently, these data imply a consistent Ba isotope offset of −0.46‰ ± 0.10‰ (±2 SD) between sinking particulates and seawater. This offset is similar to those determined in previous studies and indicates that it applies to particulates formed across diverse environmental conditions. Third, barite-containing sediment samples deposited in the GOA exhibit δ¹³⁸Ba = +0.34‰ ± 0.03‰, which is offset by approximately +0.2‰ relative to sinking particles. While the specific mechanism driving this offset remains unresolved, our results highlight the importance of performing site-specific proxy validations and exercising careful site selection when applying novel paleoceanographic proxies. 

In the modern marine environment, barium isotope (δ138Ba) variations are primarily driven by barite cycling – barite incorporates “light” Ba isotopes from solution, rendering the residual Ba reservoir enriched in “heavy” Ba isotopes by a complementary amount. Since the processes of barite precipitation and dissolution are vertically segregated and spatially heterogeneous, barite cycling drives systematic variations in the barium isotope composition of seawater and sediments. This Element examines these variations; evaluates their global, regional, local, and geological controls; and, explores how δ138Ba can be exploited to constrain the origin of enigmatic sedimentary sulfates and to study marine biogeochemistry over Earth’s history. 

It has been hypothesized that the overall size of—or efficiency of carbon export from—the biosphere decreased at the end of the Great Oxidation Event (GOE) (ca. 2,400 to 2,050 Ma). However, the timing, tempo, and trigger for this decrease remain poorly constrained. Here we test this hypothesis by studying the isotope geochemistry of sulfate minerals from the Belcher Group, in subarctic Canada. Using insights from sulfur and barium isotope measurements, combined with radiometric ages from bracketing strata, we infer that the sulfate minerals studied here record ambient sulfate in the immediate aftermath of the GOE (ca. 2,018 Ma). These sulfate minerals captured negative triple-oxygen isotope anomalies as low as ∼ −0.8‰. Such negative values occurring shortly after the GOE require a rapid reduction in primary productivity of >80%, although even larger reductions are plausible. Given that these data imply a collapse in primary productivity rather than export efficiency, the trigger for this shift in the Earth system must reflect a change in the availability of nutrients, such as phosphorus. Cumulatively, these data highlight that Earth’s GOE is a tale of feast and famine: A geologically unprecedented reduction in the size of the biosphere occurred across the end-GOE transition.